Read e-book online Acetic Acid and its Derivatives (Chemical Industries) PDF

By Victor H. Agreda

ISBN-10: 0585346054

ISBN-13: 9780585346052

ISBN-10: 0824787927

ISBN-13: 9780824787929

Extraordinary a stability among easy chemistry and chemical engineering, this updated reference discusses very important points of acetic acid and its significant derivatives, together with chemistry, equipment of instruction and manufacture, and synthesis, in addition to present and rising downstream technologies.;The ebook offers finished actual estate info for compounds and their separation, together with acetic acid-water separation. Describing 5 different types of concepts for the manufacture of acetic acid, it: examines thermophysical houses and aqueous options, with distinct causes of mathematical types and correlations; provides a serious research of estate; outlines production bills and similar financial components; experiences the functions of acetic acid and derivatives; covers the chemistry and education of the derivatives; elucidates contemporary issues reminiscent of deicers, esters and new esterification applied sciences.

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S. Patent 4,285,875 (1981). 46. Pedersen, S. , Hardman, H. , and Wagner, L. S. Patent 4,408,071 (1983). < previous page page_24 next page > page_25 < previous page page_25 next page > Page 25 47. S. Patent 4,094,901 (1978). 48. , Park Ridge, New Jersey, 1967, p. 6. 49. Hobbs, C. , and Van't, H. S. Patent 3,914,296 (1975). 50. McCain, J. , and Kaiser, S. , European Patent Appl. EP 294,846 (1988). 51. Shakhtakhtinskii, T. , Aliev, A. , Kuliev, A. , Mamedov, F. , Babaeva, A. , Naraevskaya, S. , and Medzhidova, S.

Ghosh, S. , Bhattacharyya, N. , and Sen, S. , in Adv. , Proc. 7th Natl. Symp. Catal. (P. ), Wiley, New York, 1985, p. 83. 23. , in Ethylene and Its Industrial Derivatives (S. A. ), Ernest Benn, London, 1969, p. 639. 24. Miller, S. , Acetylene, Its Properties, Manufacture, and Uses, Vol. 2, Academic Press, New York, 1966, p. 150. 25. Lowenheim, F. , and Moran, M. , Wiley-Interscience, New York, 175, p. 1. 26. , 55, 97 (1976). 27. Ma, J. J. , Acetaldehyde, Report No. 24A2, Stanford Research Institute, Menlo Park, CA, 1976.

2) [22]. [The equilibrium shown in Eq. ] Thus, one additional role of iodide salts might be to accelerate the consumption of the methyl acetate intermediate. The acetate salt would be expected to rapidly react with HI or HCo(CO)4 to generate I or Co(CO)4, respectively. This would likely accelerate the reaction further by accelerating the rate at which the most likely reactive cobalt intermediate, Co(CO)4, is cycled through the reaction. A schematic design of the cobalt-based carbonylation plant operated by BASF has been published [1] but will not be reproduced here because it represents antiquated technology.

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Acetic Acid and its Derivatives (Chemical Industries) by Victor H. Agreda

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